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Visible-light photoredox catalysis has been proved to be a powerful preparative tool owing to its environmental benignity and mechanistic versatility in promoting a large number of synthetically important reactions with high levels of selectivity. Pertaining to their unique biological, physical, and chemical properties, ﬂuoroalkylated organic substances have attracted signiﬁcant attention from researchers in a variety of disciplines. Fluoroalkylated compounds are considered particularly important in pharmaceutical chemistry because of their superior lipophilicity, binding selectivity, metabolic stability, and bioavailability to those of their nonﬂuoroalkylated analogues. Our group has continuously been involved in the development of various methods for the synthesis of ﬂuoroalkylated substances that rely on the use of visible-light photoredox catalysis. We developed visible-light photocatalytic methods for the introduction of a variety of ﬂuoroalkyl groups (such as, −CF3, −CF2R, −CH2CF3, −C3F7, and −C4F9) arylthioﬂuoroalkyl groups (such as, −CF2SPh, −C2F4SAr, and −C4F8SAr) and oxyfluoroalkyl groups (such as, −CF2OPh, and –(CF2)2OPh) to organic substances. We are continuously striving for the development of state-of-the-art fluorination and fluoroalkylation methods under mild reaction conditions.